JAMB Chemistry · Section A
Study notes for Solubility — part of the JAMB UTME Chemistry syllabus. 13 learning objectives with explanations and exam tips.
A solubility curve is simply a graph showing how much of a substance can dissolve in water at different temperatures. The x-axis shows temperature in degrees Celsius, while the y-axis shows how many grams of solute dissolve in 100g of water. As you move along the curve from left to right, you're essentially watching what happens when you heat your solution.
Most solid salts become more soluble as temperature increases, so their curves slope upward. Think of adding table salt to hot water versus cold water—hot water accepts more salt. The curve helps you predict exactly how much will dissolve at any given temperature. For example, sodium chloride (common salt) shows relatively small changes in solubility with temperature compared to potassium nitrate, which changes dramatically.
Solubility tells you the maximum mass of a substance that dissolves in 100g of solvent at a particular temperature. To calculate how much solute can dissolve, you use the relationship: if 30g of salt dissolves in 100g of water, then in 250g of water, you can dissolve (30 × 250) ÷ 100 = 75g of salt.
Think of it like this: Nigerian salt factories know that at 25°C, about 36g of table salt dissolves in 100g of water. If a factory needs to make brine solution using 500g of water, they calculate that 180g of salt will dissolve completely.
The formula is: mass of solute = (solubility × mass of solvent) ÷ 100
Master this proportion method because it appears repeatedly in JAMB papers.
Solubility simply means how much of a substance can dissolve completely in a given amount of solvent at a specific temperature. Think of it like this: when you add salt to a cup of water, the salt dissolves up to a certain point. Add too much salt, and some grains will remain at the bottom undissolved. That maximum amount that dissolved completely is the solubility of salt in water.
Different substances have different solubility levels. Sugar dissolves more easily in hot water than cold water, which is why your tea tastes sweeter when hot. In Nigeria, when you prepare "zobo" drink, the more water you use, the less concentrated it becomes because the hibiscus solute spreads through more solvent.
Temperature usually affects solubility greatly. Most solid solutes become more soluble in hot solvents, while gases become less soluble in hot water, which is why boiled water releases bubbles.
Solubility simply means how much of a substance can dissolve in a liquid at a particular temperature. Think of it like adding sugar to your tea—when the water is hot, the sugar dissolves quickly and completely. But if you try dissolving sugar in cold water, it takes much longer and some grains might remain undissolved at the bottom.
For most solid substances like salt and sugar, solubility increases as temperature increases. This is why hot water dissolves things faster than cold water. However, some substances like calcium hydroxide behave differently—they actually become less soluble in hotter water.
When you're dissolving a substance, the temperature really matters. A solution that's saturated at 50°C might not be saturated anymore if you cool it to 30°C, causing crystals to form.
Solubility is temperature-dependent, meaning the amount of substance that dissolves in a liquid changes with temperature. When you heat a solution, more solute dissolves because the increased thermal energy helps break apart the solid structure and keeps particles in solution. This is why sugar dissolves faster in hot tea than cold water—heat provides the energy needed to separate sugar particles.
Most solid solutes show increased solubility at higher temperatures. However, some substances like calcium hydroxide actually dissolve less in hot water than cold water, showing inverse temperature dependence.
A perfect Nigerian example is making concentrated salt solution for cooking. If you add salt to hot water, much more dissolves compared to adding the same amount to cold water.
The nature of a solvent determines what it can dissolve and how well it works for different purposes. Polar solvents like water dissolve ionic and polar substances effectively because their molecules have positive and negative ends that attract charged particles. This is why water is used for dissolving salts and sugars in cooking and industrial processes across Nigeria. Non-polar solvents like petrol dissolve oils, fats, and greases instead, making them perfect for cleaning tasks. This principle—"like dissolves like"—means we choose solvents based on what we need to dissolve. In Nigerian laundries, petrol removes stubborn oil stains from clothes because oil is non-polar, while water alone cannot. Understanding a solvent's polarity helps us select the right one for any job, whether cleaning, cooking, or manufacturing.
A true solution is a homogeneous mixture where a solute completely dissolves in a solvent, forming a single phase. The solute particles are so tiny (molecular or ionic level) that they're invisible even under a microscope, and the mixture appears completely clear and transparent. Think of salt dissolving in water to make brine—you cannot see the salt particles anymore because they've dissolved completely into the liquid.
In Nigeria, a perfect example is sugar dissolving in tea or palm wine. Once the sugar dissolves, you get a uniform, clear liquid throughout. Unlike suspensions where particles remain visible, or colloids where particles scatter light, true solutions are perfectly uniform. The solute won't settle at the bottom no matter how long you leave it.
True solutions have important characteristics: they conduct electricity only if the solute is ionic, they're transparent, and their particles cannot be separated by filtration.
When a substance doesn't fully dissolve in a liquid, it forms either a suspension or a colloid. Think of suspensions like palm oil mixed with water—the oil particles are large and eventually settle at the bottom. You'll see the mixture is cloudy and the particles separate over time.
Colloids are different. Imagine milk or the creamy texture of tomato sauce. The particles are so tiny they stay spread throughout the liquid, making it appear uniform. These particles won't settle easily because they're constantly moving around. In Nigeria, examples include palm wine which appears clear but contains colloidal particles, and locust bean soup which has that characteristic cloudy appearance.
The key difference: suspensions have large particles that settle; colloids have tiny particles that stay suspended indefinitely. Both look different from true solutions where everything dissolves completely invisible.
A true solution is when a substance completely dissolves in a liquid, forming a homogeneous mixture where all particles are uniformly distributed. Think of it like this: when you dissolve sugar in water to make juice, the sugar disappears completely and you cannot see or separate it anymore. The mixture is transparent and the solute particles are so small they remain suspended at the molecular level.
In Nigeria, a common example is salt dissolved in water. When you add table salt to water, it dissolves completely and becomes invisible, but you can taste the saltiness throughout the liquid. This is a true solution, not a suspension.
What makes true solutions different from suspensions is that the particles stay permanently dissolved and won't separate even if you wait for days. The mixture also conducts electricity because ions are free to move.
A true solution is a homogeneous mixture where a solute dissolves completely into a solvent at the molecular level. When sugar dissolves in water to make sweet water, you get a true solution—the sugar particles are so tiny they're invisible, and the mixture looks clear and uniform throughout.
A false solution, also called a colloidal suspension, looks like a solution but isn't completely dissolved. Think of the traditional palm wine sellers in Lagos who add cornstarch to their drinks. The cornstarch particles float around suspended in the liquid, making it slightly cloudy. If you leave it standing, the particles eventually settle at the bottom.
The key difference is that true solutions are transparent and stable, while false solutions scatter light and can separate over time.
A suspension is a mixture where solid particles are dispersed throughout a liquid but do not dissolve. The particles remain visible and will eventually settle at the bottom if left undisturbed. Think of it like this: the solid particles are just floating around in the liquid, not actually becoming part of it.
Consider palm wine with sediment at the bottom—that's a perfect Nigerian example. The particles suspend in the liquid but separate over time. Other common suspensions include muddy water, chalk powder mixed with water, and the mixture you get when you stir flour into water.
The key difference from solutions is that suspensions are cloudy and you can see the particles with your naked eye. If you leave a suspension standing, gravity pulls the particles down, forming a layer at the bottom.
Solubility is how much of a substance can dissolve in a liquid, usually water, at a specific temperature. When you add salt to water, it dissolves completely because salt is highly soluble. However, if you keep adding more salt, eventually no more will dissolve—that's the saturation point. Think of making garri in Nigeria; you can only dissolve so much garri powder in water before it becomes too thick and won't mix properly anymore.
Colloids are different from solutions. They're mixtures where tiny particles float around but don't fully dissolve. Evaporated milk is a perfect Nigerian example of a colloid—the fat particles stay suspended in the liquid without settling. Unlike true solutions, colloids appear cloudy and scatter light visibly.
Understanding these differences matters because solutions are transparent while colloids look murky or milky.
Solubility is simply the ability of a substance to dissolve in a solvent, usually water. Some substances dissolve easily while others don't, and there are clear reasons for this. The main reason involves the chemical nature of both the solute and solvent. Polar substances like salt dissolve well in polar solvents like water because they have similar molecular structures—we say "like dissolves like." When you add salt to water in your kitchen, the water molecules surround salt crystals and pull them apart into individual ions, allowing them to dissolve completely.
Non-polar substances like oil don't dissolve in water because their molecules are too different from water's polar nature. Temperature also affects solubility significantly; heating water generally increases how much sugar or salt can dissolve in it. The particle size of the solute and how much you stir the mixture influence the speed of dissolving too.